Probably too late, but I use photoshop from the start and my advice is to try different styles of graphic and genre to find her own style and the best genre she can make... ^^
If you can, get Photoshop.
If you can't, then I highly recommend GIMP. GIMP is free and similar to Photoshop (with other exceptions, of course). However, GIMP is a good place to start if you're looking for a free software that's similar to Photoshop. I know that along with Photoshop, there are GIMP tutorials on this site.